120974-97-2
- Product Name：METHYL 2-（METHOXYIMINO）-2-O-TOLYLACETATE
- Molecular Formula：C11H13NO3
- Purity：99%
- Molecular Weight：207.229
Product Details
pd_meltingpoint:66-68℃
Reputable factory supply METHYL 2-（METHOXYIMINO）-2-O-TOLYLACETATE 120974-97-2 in stock with high standard
- Molecular Formula:C11H13NO3
- Molecular Weight:207.229
- Melting Point:66-68℃
- Boiling Point:282℃
- Flash Point:117℃
- PSA：47.89000
- Density:1.07
- LogP:1.51850
120974-97-2 Relevant articles
Synthesis and fungicidal activity of (E)-α-(Methoxyimino)benzeneacetate derivatives containing 1,2,4-triazole schiff base side Chain
Song, Hong-Xing,Shi, De-Qing
, p. 1345 - 1348 (2015)
Figure presented To find new strobilurin...
Preparation method of (E)-2-methyl-alpha-methoxyimino methyl phenylacetate and intermediate thereof
-
Paragraph 0080-0107, (2021/05/29)
The invention provides a preparation met...
(E)-2-(2-tolyl)-2-methoxyimino methyl acetate preparation method
-
Paragraph 0051; 0054; 0055; 0058, (2020/03/09)
The invention provides a (E)-2-(2-tolyl)...
Intermediate for preparing trifloxystrobin and synthesis method of intermediate
-
, (2020/11/01)
The invention relates to an intermediate...
AN IMPROVED PROCESS FOR THE PREPARATION OF TRIFLOXYSTROBIN
-
Page/Page column 15; 16, (2019/04/10)
The present invention relates to an impr...
120974-97-2 Process route
-
-
67-56-1
methanol
-
-
2-methoxyimino-2-(o-tolyl)acetic acid
-
-
120974-97-2
methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate
| Conditions | Yield |
|---|---|
|
2-methoxyimino-2-(o-tolyl)acetic acid;
With
bis(trichloromethyl) carbonate;
In
1,2-dichloro-ethane; N,N-dimethyl-formamide;
at 40 - 60 ℃;
methanol;
for 2h;
Reagent/catalyst;
Reflux;
|
95% |
|
2-methoxyimino-2-(o-tolyl)acetic acid;
With
thionyl chloride;
In
dichloromethane; N,N-dimethyl-formamide;
at 40 - 45 ℃;
for 8h;
methanol;
at 60 - 65 ℃;
for 1h;
|
61 g |
-
-
methyl 2-iodo-2-methoxyiminoacetate
-
-
2-methylphenylzinc bromide
-
-
120974-97-2
methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate
| Conditions | Yield |
|---|---|
|
With
1,2-bis(diphenylphosphino)ethane nickel(II) chloride; 1,2-bis-(diphenylphosphino)ethane;
In
N,N-dimethyl acetamide;
at 30 ℃;
for 3h;
Inert atmosphere;
|
85% |
120974-97-2 Upstream products
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178240-01-2
methyl (E)-2-hydroxyimino-2-o-tolylacetate
-
77-78-1
dimethyl sulfate
-
2028-34-4
o-toluene-diazonium chloride
-
34966-54-6
methyl 2-oxo-2-(o-tolyl)acetate
120974-97-2 Downstream products
-
133409-72-0
methyl (E)-2-[2-(bromomethyl)phenyl]-2-(methoxyimino)acetate
-
189177-71-7
methyl (E)-α-(methoxyimino)-2-(aminoxymethyl)benzeneacetate
-
156581-14-5
methyl (2E)-2-[2-[(1,3-dioxoisoindolin-2-yl)oxymethyl]phenyl]-2-methoxyiminoacetate
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